No with DoCmd.transferspreadsheet - it is just a dumb transfer. Built-in one-size-fits-all.
One way is to push it into a template.
My suggestion is to use this more complex method.
http://www.btabdevelopment.com/ts/default.aspx?PageId=48
Suggest that you embrace coding to take total control of your Excel outputs.
Once you have mastered the code on the link above, if Column B needed to be set to currency, the code to add would something like this.
APXL.Columns("B:B").Select
With ApXL.Selection
.NumberFormat = "$#,##0.00"
end with
After using code with a query to bring over the data to Excel, a set of code can be used to make very verbose reports.
This is sometimes called "Topping Off" the data transfer.
I never use the Access reports. Everything is in Excel.
The Data Headers always start on line 5. This leaves room on top to add custom formulas for a Dashboard. Since the number of records returned is known, the formulas are customized.
Each user selects the criteria for each Excel Report. The resulting report is named and time stamped. The name includes the parameter criteria selected by the user.
The report is then saved on a network location - under each Users Folder, then under the Report name. Basically a filing system.
The attachment shows a typical report. Cell B4 has a custom formula designed for the exact number of records returned.
You can make out the Bold and light rows that indicate the latest and multiple records. The Filters allow things like Bold only, and other column filters. The formula can count only those visible, only those bold and just about anything else a regulatory manager can think of.
More important: These Smart Excel reports allow managers to perform live "what if" decisions during meetings.
While you won't start doing this level of Excel day one, learning the basics from the web site above will be very useful to your career.
This is a long-winded explanation. This same question is asked several times a month. This link might be re-posted. Otherwise, I might turn into one of those Pirate's Parrot.