I'm taking the width of the form (13.76)
the width of the form (which is what you design) is not the same as the width of the window (which is where the form is displayed i.e. what you see)
the window may be much wider or narrower that the form. Same for height. The form can be much bigger than even the monitor.
Just hiding/showing the ribbon and/or navigation pane will make a difference to the height/width of the window. Similarly showing access full screen or not.
You asked about centralising a rectangle on a form. I suspect you should be asking how to centralise a rectangle in a window.
If you are, use what I suggested at the end of my first post. And if you want it to be dynamic - i.e. stay centred if you resize the window, put it in the form resize event.
I don't use them but if you are using 2007 or later, there are also the anchor properties which may do what you want.